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词汇 Melting point depression
分类 英语词汇 英语翻译词典
释义

Melting point depression

英语百科

Melting-point depression

(重定向自Melting point depression)
Figure 1. A normalized melting curve for gold as a function of nanoparticle diameter. The bulk melting temperature and melting temperature of the particle are denoted TMB and TM respectively. Experimental melting curves for near spherical metal nanoparticles exhibit a similarly shaped curve.
Figure 2. A Lennard-Jones potential energy curve. The model shows the interactive energy between 2 atoms at a normalized distance, d/d0, where d0=atomic diameter. The interaction energy is attractive where the curve is negative, and the magnitude of the energy represents the cohesive energy between a pair of atoms. Note that the attractive potential extends over a long range beyond the length of a chemical bond, so atoms experience cohesive energy with atoms further than their nearest neighbors.
This article deals with melting/freezing point depression due to very small particle size. For depression due to the mixture of another compound, see freezing-point depression.

Melting-point depression is the phenomenon of reduction of the melting point of a material with reduction of its size. This phenomenon is very prominent in nanoscale materials, which melt at temperatures hundreds of degrees lower than bulk materials.

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