网站首页  情感咨询  情感美文  情感百科  情感生活  学习充电  旧版美文

请输入您要查询的词汇:

 

词汇 Wharton reaction
分类 英语词汇 英语翻译词典
释义

Wharton reaction

中文百科

沃顿反应

沃顿反应Wharton反应)是 α,β-环氧酮类在肼作用下转变为烯丙醇的反应。 反应以彼得·斯坦利·沃顿(Peter Stanley Wharton)的名字命名。

这个反应是立体专一的,原料环氧化物的构型在产物醇中得到保持。 这个方法广泛用于甾类化学中。

Dupuy改进法:

英语百科

Wharton reaction 沃顿反应

The Wharton olefin synthesis is a chemical reaction that involves the reduction of α,β-epoxy ketones using hydrazine to give allylic alcohols. This reaction, introduced in 1961 by P. S. Wharton, is an extension of the Wolff–Kishner reduction. The general features of this synthesis are: 1) the epoxidation of α,β-unsaturated ketones is achieved usually in basic conditions using hydrogen peroxide solution in high yield; 2) the epoxy ketone is treated with 2–3 equivalents of a hydrazine hydrate in presence of substoichiometric amounts of acetic acid. This reaction occurs rapidly at room temperature with the evolution of nitrogen and the formation of an allylic alcohol. It can be used to synthesize carenol compounds. The Wharton reaction is the chemical reaction of α,β-epoxy-ketones with hydrazine to give allylic alcohols. Wharton's procedure has been improved.

随便看

 

依恋情感网英汉例句词典收录3870147条英语例句词条,基本涵盖了全部常用英语单词的释义及例句,是英语学习的有利工具。

 

Copyright © 2004-2024 Yiyi18.com All Rights Reserved
京ICP备2021023879号 更新时间:2025/8/9 23:30:44