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词汇 Hinsberg reaction
分类 英语词汇 英语翻译词典
释义

Hinsberg reaction

中文百科

兴斯堡反应

Hinsberg反应是一种胺的化学鉴定方法。它可以很好地区分一级胺、二级胺和三级胺。这个反应中需将胺与Hinsberg试剂在碱金属氢氧化物存在下混合均匀。然后将氢氧化钠水溶液和苯磺酰氯的混合试剂加入。一级胺形成的磺酰胺可溶于碱。二级胺则形成不溶性的磺酰胺沉淀。三级胺不与苯磺酰氯反应。加入稀酸后不溶性的胺可转化成可溶性的铵盐。这个反应因此可用于区分三种胺。

Hinsberg反应最早由奥斯卡·兴斯堡于1890年发现。

英语百科

Hinsberg reaction 兴斯堡反应

The Hinsberg reaction is a chemical test for the detection of amines. It is an excellent test for distinguishing primary, secondary and tertiary amines. In this test, the amine is shaken well with Hinsberg reagent in the presence of aqueous alkali (either KOH or NaOH). A reagent containing an aqueous sodium hydroxide solution and benzenesulfonyl chloride is added to a substrate. A primary amine will form a soluble sulfonamide salt which precipitates after addition of diluted hydrochloric acid. A secondary amine in the same reaction will directly form an insoluble sulfonamide. A tertiary amine will not react with the sulfonamide but is insoluble. After adding dilute acid this insoluble amine is converted to a soluble ammonium salt. In this way the reaction can distinguish between the three types of amines.

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