Condensed tannin

Condensed tannins (proanthocyanidins, polyflavonoid tannins, catechol-type tannins, pyrocatecollic type tannins, non-hydrolyzable tannins or flavolans) are polymers formed by the condensation of flavans. They do not contain sugar residues.

They are called proanthocyanidins as they yield anthocyanidins when depolymerized under oxidative conditions. Different types of condensed tannins exist, such as the procyanidins, propelargonidins, prodelphinidins, profisetinidins, proguibourtinidins or prorobinetidins, formed from flavonoids structures corresponding to the related anthocyanins. One particular type of condensed tannin, found in grape, are procyanidins, which are polymers of 2 to 50 (or more) flavan-3-ol units joined by carbon-carbon bonds. These are not susceptible to being cleaved by hydrolysis.