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词汇 Organolithium compound
分类 英语词汇 英语翻译词典
释义

Organolithium compound

中文百科

有机锂试剂 Organolithium reagent

(重定向自Organolithium compound)

有机锂试剂是含有碳原子与锂原子直接成键的一类有机金属化合物。锂原子具有天然的电正性,因此有机锂化合物的大部分电荷密度被推向了化学键上的碳原子一端,从而易形成碳负离子。有机锂化合物是一种极强的碱和亲核试剂。

英语百科

Organolithium reagent 有机锂试剂

(重定向自Organolithium compound)
Glass bottles containing butyllithium
sec-Butyllithium aggregate
Solid state structures of methyllithium tetramers, n-butyllithium hexamers and polymeric ladder of phenyllithium

Organolithium reagents are organometallic compounds that contain carbon – lithium bonds. They are important reagents in organic synthesis, and are frequently used to transfer the organic group or the lithium atom to the substrates in synthetic steps, through nucleophilic addition or simple deprotonation. Organolithium reagents are used in industry as an initiator for anionic polymerization, which leads to the production of various elastomers. They have also been applied in asymmetric synthesis in the pharmaceutical industry.

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