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词汇 Diazo Compound
分类 英语词汇 英语翻译词典
释义

Diazo Compound

中文百科

重氮化合物 Diazo

(重定向自Diazo Compound)

重氮化合物(Diazo)是一类含氮的有机化合物,通式为R2C=N2,一般指脂肪族重氮化合物,大多具爆炸性。重氮化合物中的重氮基有多个共振式,中间氮原子带有部分正电荷,两端的碳和氮原子带负电荷。α-重氮酮和α-重氮酯中的负电荷可以离域到羰基上去,因此比较稳定。

最简单的重氮化合物是重氮甲烷,是个不稳定的黄色气体。除重氮甲烷外,重氮乙酸乙酯(N2CHCOOEt)也是较常用的重氮化合物。

另一个与重氮化合物类似的官能团是(双吖丙啶)Diazirine,是含有由两个氮原子和一个碳原子组成的三元环的衍生物。

重氮化合物有如下共振式:

英语百科

Diazo 重氮化合物

(重定向自Diazo Compound)

Diazo refers to a type of organic compound called diazo compound that has two linked nitrogen atoms (azo) as a terminal functional group. The general formula is R2C=N2. The simplest example of a diazo compound is diazomethane. The electronic structure of diazo compounds involves a positive charge on the central nitrogen and negative charge distributed between the terminal nitrogen and the carbon. Some of the most stable diazo compounds are α-diazo-ß-diketones and α-diazo-ß-diesters since the negative charge is delocalized into the carbonyls. In contrast, most alkyldiazo compounds are explosive. A commercially relevant diazo compound is ethyl diazoacetate (N2CHCOOEt). A group of isomeric compounds with only few similar properties are the diazirines, where the carbon and two nitrogens are linked as a ring.

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