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词汇 Chromocene
分类 英语词汇 英语翻译词典
释义

Chromocene

中文百科

二茂铬

Cromoceno: Conformación alternada (izquierda) y conformación eclipsada (derecha).

二茂铬是一种有机金属化合物,化学式(C5H5)2Cr。遇空气迅速氧化,有时会自燃。溶于液氨、四氢呋喃等。可由二氯化铬与环戊二烯基钠在四氢呋喃中反应制得:

CrCl2 + 2 NaC5H5 → Cr(C5H5)2 + 2 NaCl

二茂铬可以用作乙烯聚合高效催化剂、氢化催化剂和硫化促进剂等。

英语百科

Chromocene 二茂铬

Cromoceno: Conformación alternada (izquierda) y conformación eclipsada (derecha).

Chromocene, formally known as bis(η-cyclopentadienyl)chromium(II), is a chemical compound with the condensed structural formula [Cr(C5H5)2]. Each molecule contains an atom of chromium bound between two planar systems of five carbon atoms known as cyclopentadienyl (Cp) rings in a sandwich arrangement, which is the reason its formula is often abbreviated as Cp2Cr. It is an organometallic compound as it has (haptic) covalent chromium–carbon bonds. Chromocene is structurally similar to ferrocene, the prototype for the metallocene class of compounds; however, as it has only 16 valence electrons, it does not follow the 18-electron rule. It is a paramagnetic compound and also highly reducing, both consequences of its low valence electron count. Like structurally related metallocenes, chromocene readily sublimes in a vacuum and is soluble in non-polar organic solvents.

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