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词汇 Bite angle
分类 英语词汇 英语翻译词典
释义

Bite angle

英语百科

Bite angle

The two phosphorus atoms (orange) of dppe have a bite angle of 85.8° on the palladium atom (blue) in [PdCl2(dppe)].
Figure 1. Dcpm, which forms a four-membered chelate ring.
Figure 3. Bite angle of a diphosphine ligand bound to Rh.
Figure 5. BISBI, a diphosphine with a bite angle of 113°.

The bite angle is a geometric parameter used to classify chelating ligands in coordination chemistry, including organometallic complexes. Although the parameter can be applied generally to any chelating ligand, it is commonly applied to describe diphosphine ligands, which can adopt a wide range of chelate ring sizes.

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