How to choose the base used in the synthesis of arsine ylide is studied. 本文主要研究了胂叶立德合成中碱的选择。
Three strategies (additive, chiral auxiliary or chiral reagent) were developed to improve the diastereoselectivity or enantioselectivity of the ylide cyclopropanation reactions. 通过添加剂、手性辅基、手性试剂等3种策略,分别控制反应的非对映选择性和对映选择性。
An ylide or ylid (/ˈɪlɪd/ or /ˈɪlaɪd/) is a neutral dipolar molecule containing a formally negatively charged atom (usually a carbanion) directly attached to a heteroatom with a formal positive charge (usually nitrogen, phosphorus or sulfur), and in which both atoms have full octets of electrons. Ylides are thus 1,2-dipolar compounds. They appear in organic chemistry as reagents or reactive intermediates.