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词汇 Transacetalization
分类 英语词汇 英语翻译词典
释义

Transacetalization

中文百科

缩醛 Acetal

(重定向自Transacetalization)
缩醛通式

缩醛Acetal)是一类同一碳上连有两个烷氧基和一个氢的有机化合物。缩醛可由半缩醛继续与醇反应得到,而半缩醛可以由醛和醇反应得到。

缩醛在酸性水溶液中是不稳定的,但对碱和氧化剂是稳定的,因此可以用作羰基的保护基。

缩醛(酮)生成的一般过程:

英语百科

Acetal 缩醛

(重定向自Transacetalization)
Structure of a generic ketal
Acetalisation Mechanism

An acetal is a functional group with the following connectivity R2C(OR')2, where both R' groups are organic fragments. The central carbon atom has four bonds to it, and is therefore saturated and has tetrahedral geometry. The two R'O groups may be equivalent to each other or not. The two R groups can be equivalent to each other (a "symmetric acetal") or not (a "mixed acetal"), and one or both can even be hydrogen atoms rather than organic fragments. Acetals are formed from and convertible to carbonyl compounds (aldehydes or ketones R2C=O). The term ketal is sometimes used to identify structures associated with ketones rather than aldehydes and, historically, the term acetal was used specifically for the aldehyde cases.

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