Thiocarbamate
![General structural formulae of O-organyl (1) and S-organyl (2) thiocarbamates](/Images/godic/202502/16/Thiocarbamates-general-2D4449.png")
Thiocarbamates are a family of organosulfur compounds. There are two isomeric forms of thiocarbamate esters: O-thiocarbamates, ROC(=S)NR2, and S-thiocarbamates, RSC(=O)NR2. O-thiocarbamates can isomerise to S-thiocarbamates, for example in the Newman-Kwart rearrangement.