Slater determinant 斯莱特行列式
In quantum mechanics, a Slater determinant is an expression that describes the wavefunction of a multi-fermionic system that satisfies anti-symmetry requirements and consequently the Pauli principle by changing sign upon exchange of two electrons (or other fermions). It is named for John C. Slater, who introduced the determinants in 1929 as a means of ensuring the antisymmetry of a wave function. But actually the wave function in the determinant form first appeared three years earlier independently in Heisenberg's and Dirac's papers. The Slater determinant arises from the consideration of a wave function for a collection of electrons, each with a wave function known as the spin-orbital,
, where
denotes the position and spin of the singular electron. Two electrons within the same spin orbital result in no wave function.