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词汇 Pseudorotaxane
分类 英语词汇 英语翻译词典
释义

Pseudorotaxane

中文百科

轮烷 Rotaxane

(重定向自Pseudorotaxane)

轮烷(Rotaxane)是一类由一个环状分子套在一个哑铃状的线型分子上的而形成的内锁型超分子体系。如果包含多个环状分子,则成为聚轮烷。

英语百科

Rotaxane 轮烷

(重定向自Pseudorotaxane)
Graphical representation of a rotaxane
Crystal structure of rotaxane with a cyclobis(paraquat-p-phenylene) macrocycle.[1]
Rotaxane synthesis can be carried out via a
Crystal structure of a rotaxane with an α-cyclodextrin macrocycle.[7]

A rotaxane is a mechanically interlocked molecular architecture consisting of a "dumbbell shaped molecule" which is threaded through a "macrocycle" (see graphical representation). The name is derived from the Latin for wheel (rota) and axle (axis). The two components of a rotaxane are kinetically trapped since the ends of the dumbbell (often called stoppers) are larger than the internal diameter of the ring and prevent dissociation (unthreading) of the components since this would require significant distortion of the covalent bonds.

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