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词汇 Peroxy
分类 英语词汇 英语翻译词典
释义

Peroxy

中文百科

过氧化物 Peroxide

(重定向自Peroxy)

过氧化物,指一类含有过氧基-O-O-的化合物,具有强氧化性,又可分为有机过氧化物与无机过氧化物。在包含过氧基的化合物中,每个氧原子的氧化数为 -1。1798年德国科学家亚历山大·冯·洪堡(Alexander von Humboldt)即制造出过氧化钡。1818年泰纳尔合成过氧化氢,即今日我们最常见的双氧水。

英语百科

Peroxide 过氧化物

(重定向自Peroxy)
Types of peroxides, from top to bottom: peroxide ion, organic peroxide, organic hydroperoxide, peracid. The peroxide group is marked in blue. R, R1 and R2 mark hydrocarbon moieties.
Degradation of hypoxanthine to uric acid to form hydrogen peroxide. XO = xanthinoxidase
Australian bombardier beetle
Firefly Lampyris noctiluca

A peroxide is a compound containing an oxygen–oxygen single bond or the peroxide anion, O2−
2
. The O−O group is called the peroxide group or peroxo group. In contrast to oxide ions, the oxygen atoms in the peroxide ion have an oxidation state of −1.

The simplest stable peroxide is hydrogen peroxide. Superoxides, dioxygenyls, ozones and ozonides are considered separately. Peroxide compounds can be roughly classified into organic and inorganic. Whereas the inorganic peroxides have an ionic, salt-like character, the organic peroxides are dominated by the covalent bonds. The oxygen–oxygen chemical bond of peroxide is unstable and easily split into reactive radicals via homolytic cleavage. For this reason, peroxides are found in nature only in small quantities, in water, atmosphere, plants, and animals. Peroxide ion formation has recently been highlighted as one of the main mechanisms by which oxides accommodate excess oxygen in ionic crystals and may have a large impact on a range of industrial applications including solid oxide fuel cells.

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