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词汇 Lithium cobaltite
分类 英语词汇 英语翻译词典
释义

Lithium cobaltite

中文百科

锂钴氧化物 Lithium cobalt oxide

(重定向自Lithium cobaltite)

锂钴氧化物,也称钴酸锂,化学式为LiCoO2,是一种无机化合物,一般使用作锂离子电池的正电极材料。LiCoO2的结构巳借助X光绕射、电子显微镜和中子粉末绕射等技术研究清楚。锂原子层处于钴和氧原子形成的正八面体的平板之间(如下图所示)。这个结构与理论预测的结构相吻合。

锂钴氧化物有毒,处理时需注意安全。

英语百科

Lithium cobalt oxide 锂钴氧化物

(重定向自Lithium cobaltite)

Lithium cobalt oxide (LiCoO
2
) is a chemical compound commonly used in the positive electrodes of lithium-ion batteries. The structure of LiCoO
2
is known theoretically and has been confirmed with techniques like x-ray diffraction, electron microscopy, neutron powder diffraction, and EXAFS: it consists of layers of lithium that lie between slabs of octahedra formed by cobalt and oxygen atoms. The space group is R\bar 3m in Hermann-Mauguin notation, signifying a rhombus-like unit cell with threefold improper rotational symmetry and a mirror plane. More simply, however, both lithium and cobalt are octahedrally coordinated by oxygen. These octahedrons are edge-sharing, and tilted relative to the layered structure. The threefold rotational axis (which is normal to the layers) is termed improper because the triangles of oxygen (being on opposite sides of each octahedron) are anti-aligned.

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