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词汇 Eyring equation
分类 英语词汇 英语翻译词典
释义

Eyring equation

中文百科

过渡态理论

Figure 1: Reaction coordinate diagram for the bimolecular nucleophilic substitution (SN2) reaction between bromomethane and the hydroxide anion
Figure 2: Potential energy diagram
Figure 3: Purine nucleoside phosphorylase reaction with inosine substrate
Figure 4: PNP transition state and immucillin-H transition state analog

过渡状态理论 (Transition state theory,TST)解释基元化学反应的反应速率。该理论假设在反应物和活化的过渡态络合物之间有一种特殊的化学平衡(准平衡)。

TST最初用于定性地解释化学反应是怎幺发生的。TST就其计算绝对反应速率常数的本来目的来说不算十分成功。因为,绝对反应速率常数的计算需要精确的知道势能面。 但是,如果一个特定的反应的速率常数可以用经验的方法测定的话,该理论能够成功地计算了标准活化焓(ΔH),标准活化熵(ΔS),和标准活化吉布斯自由能(ΔG)。(所表示的是在过渡状态时所感兴趣的值。)

英语百科

Eyring equation 过渡态理论

The Eyring equation (occasionally also known as Eyring–Polanyi equation) is an equation used in chemical kinetics to describe the variance of the rate of a chemical reaction with temperature. It was developed almost simultaneously in 1935 by Henry Eyring, Meredith Gwynne Evans and Michael Polanyi. This equation follows from the transition state theory (aka, activated-complex theory) and is trivially equivalent to the empirical Arrhenius equation which are both readily derived from statistical thermodynamics in the kinetic theory of gases.

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